Calculate Mass of Chlorine in PbCl4 Sample using Mass Conservation

Published on March 2, 2026

Word-Problem

Determine the mass of Chlorine (Cl) in a 37.11 g sample of PbCl4 by subtracting the given mass of Lead (Pb) from the total sample mass.

Question

Answer

This is a stoichiometry problem that can be solved using the Law of Conservation of Mass and the concept of percent composition by mass.
Here is the step-by-step solution:
1. Identify the given information:
  • Total mass of the sample ( ):
  • Mass of Lead ( ) in the sample ( ):
2. Determine the mass of Chlorine ( ) in the sample.
Since the sample is composed only of and (in the compound ), the total mass is the sum of the masses of its components:
We can rearrange this equation to find the mass of :
Substitute the given values:
3. Final Answer Check (Optional: Calculate theoretical percent composition to verify consistency, although not required by the question):
First, we need the molar masses:
  • Molar mass of ( )
  • Molar mass of ( )
  • Molar mass of ( ):
The theoretical mass percentage of in is:
The actual mass percentage of in the sample is:
Since the percentages are very close, the initial calculation based on the conservation of mass is correct for the given sample.
The mass of in the sample is .
The final answer is .